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Lithium vs alkaline batteries

Lithium and alkaline AA and AAA batteries are the same size and both 1.5 V, so either one fits by size. Where a device’s manual names one type, fit that type.

The manual asks for

You have

Lithium or alkaline

Energizer’s lithium and alkaline AA side by side

Energizer L91 lithium AA and E91 alkaline AA, from their datasheets
Lithium AA (L91)Alkaline AA (E91)
Nominal volts1.5 V1.5 V
Weight15 g23.0 g
Shelf life25 years at 21°C10 years at 21°C
Works from-40 to 60°C-18 to 55°C
ChemistryLithium iron disulfideZinc manganese dioxide
IEC codeFR6LR6

The AAA pair, Energizer’s L92 and E92, keep the same 25-year and 10-year shelf lives on their sheets.

Energizer’s lithium handbook rates lithium’s leakage resistance “Superior” and alkaline’s “Good”, and its product page calls Ultimate Lithium “100% leak proof”, qualified as “based on standard use”.

Devices whose makers name one type

Which type each maker asks for, in its manual or help pages
DeviceType its maker names
Google Nest ProtectEnergizer Ultimate Lithium AA (L91); no alkaline or rechargeable
Blink battery cameras and Video DoorbellAA 1.5 V lithium, non-rechargeable
Kidde COB and COP CO alarms (AA models)Alkaline AA: Energizer E91, Gold Peak 15A or Golden Power GLR6A; no lithium
Google Nest Thermostat1.5 V AAA alkaline
Schlage Encode and ConnectFour AA alkaline
August smart locks, except the Wi-Fi Smart LockFour AA alkaline

From each maker’s own pages. Another device’s manual is the one to follow.

August says that with lithium or rechargeable batteries, its smart locks other than the Wi-Fi Smart Lock may not give reliable low battery alerts.

Don’t mix them in one device

Energizer’s lithium handbook says not to mix its lithium AA with used batteries or other battery types, and Duracell says mixing types in one device may cause the batteries to leak. Change the whole set at once.

Common questions

Is a lithium AA battery rechargeable?

No. Energizer's lithium handbook says its lithium iron disulfide AA and AAA cells are not designed to be recharged.

Can a lithium AA damage a device made for alkaline?

Not usually, by Energizer's lithium handbook: a fresh lithium AA reads up to 1.83 V before it's under load, and the handbook says this will typically not damage electronic components. Follow the manual where it rules lithium out: Kidde's CO alarm guides say not to use lithium.

Why does my battery tester say a lithium AA is fine when the device says it's flat?

Energizer's lithium handbook says a lithium AA reading 1.6 V is already discharged, though an alkaline at 1.6 V may read good. It counts a lithium AA under 1.70 V as completely discharged.

Where we get our information from

Volts, weights, shelf life and temperatures come from Energizer’s datasheets and handbooks; which type each device takes from its maker’s own manual or help pages, read on October 25, 2026. Checked against published data from Energizer, Blink, Google, Kidde and Schlage (plus 2 more).

See all 17 sources
  • Energizer, E91 AA alkaline product datasheet (PDF)
  • Energizer, E92 AAA alkaline product datasheet (PDF)
  • Google Nest Help, Replace Nest Protect's batteries
  • Energizer, L91 AA lithium product datasheet (PDF)
  • Kidde, Battery Powered Carbon Monoxide Alarms user guide (G-000069-00: COB, COBD, COBDL, COB10, COBD10, COBDL10), PDF
  • Kidde, AC Plug-In Carbon Monoxide Alarms user guide (G-000068-00: COP, COPD, COPDL10, COPDLG), PDF
  • Google Nest Help, How to change Nest Thermostat batteries
  • Blink Support, Blink Video Doorbell Technical Specifications
  • Blink Support, Video Doorbell (2nd Gen) Technical Specifications
  • Blink Support, How to Power your Blink Camera
  • Schlage: Encode and Connect smart deadbolt tip sheets (PDF), and the Encode BE489WB product page
  • August support: August Wi-Fi Smart Lock FAQ; Why is My Lock Flashing Red?
  • Energizer, L92 Ultimate Lithium AAA product datasheet (PDF)
  • Energizer, Cylindrical Primary Lithium Handbook and Application Manual, lithium iron disulfide (PDF)
  • Energizer, Alkaline Manganese Dioxide Handbook and Application Manual (PDF)
  • Energizer, Ultimate Lithium batteries product page
  • Duracell, Frequently Asked Questions

Battery sizes come from battery makers' datasheets and device makers' own manuals and help pages. Check your device's manual or the old battery before you buy. If anyone may have swallowed a battery, call the National Battery Ingestion Hotline at 1-800-498-8666 or your poison center at 1-800-222-1222 straight away.